Thanks, actually that will teach me for buying cheap.
When I was sourcing parts, I was looking for an LM2577 part and came across a XL6009 which seemed to be similarly specified. However, having just done some more in-depth googling, seems the XL6009 is a poorly designed load of junk, that is potentially harmful to the kit it's attached to.
This might also explain when after I set the output to 16V and then when actually placing it in the circuit a week or so later, when checking the output it had changed to a lower value. It was stored in the house, in a box, inside my electronics crate (a plastic storage box), so no jolts or friction against other items, could have changed the potentiometer.
So, I've spent a bit more (quite a bit more, with this being the Nordics

) on a LM2587 based converter, which should hopefully be more reliable. Just hope the mounting holes line up broadly with the old unit, otherwise I'll be turning the box into swiss cheese!
Thank you Mark and thanks to all for your assistance, I'll post back once I've swapped them out.